This issue can happen when using amavis.
In case you have a double email signature you can edit your postfix config.
However, mostly double dkim is NOT an issue, you need to be sure that your dkim signature is added on the DNS servers (if you are using an external DNS).
File: /etc/postfix/master.cf
smtp inet n - n - - smtpd -o content_filter=smtp-amavis:127.0.0.1:10024 -o receive_override_options=no_address_mappings
After no_address_mappings add no_milters , example:
smtp inet n - n - - smtpd -o content_filter=smtp-amavis:127.0.0.1:10024 -o receive_override_options=no_address_mappings,no_milters
After changes restart postfix:
service postfix restart